Document Details Document Type : Article In Journal  Document Title : 2-(1H-1,3-Benzodiazol-2-ylsulfanyl)-1-(4-chlorophenyl)ethanone 2-(1H-1,3-Benzodiazol-2-ylsulfanyl)-1-(4-chlorophenyl)ethanone   Subject : Chemistry  Document Language : English  Abstract : The mol-ecule in the structure of the title compound, C15H 11ClN2OS, displays two planar residues [r.m.s. deviation = 0.014 Å for the benzimidazole residue, and the ketone group is co-planar with the benzene ring to which it is attached forming a O-C-C-C torsion angle of -173.18 (14) °] linked at the S atom. The overall shape is based on a twisted V, the dihedral angle formed between the two planes being 82.4 (2) °. The amine-H atom is bifurcated, forming N-H⋯O and N-H⋯S hydrogen bonds leading to dimeric aggregates. These are linked into a supra-molecular chain along the c axis via C-H⋯π hydrogen bonds. Chains form layers in the ab plane being connected along the c axis via weak π-π interactions [3.9578 (8) Å] formed between centrosymmetrically related chloro-substituted benzene rings.  ISSN : 1600-5368  Journal Name : Acta Crystallographica Section E: Structure Reports Online  Volume : 67  Issue Number : 10  Publishing Year : 1432 AH 2011 AD  Article Type : Article  Added Date : Tuesday, December 6, 2011  Researchers Researcher Name (Arabic) Researcher Name (English) Researcher Type Dr Grade Email Hatem A Abdel-Aziz Abdel-Aziz, Hatem A Researcher Doctorate hatem_741@yahoo.com Seik Weng Ng Ng, Seik Weng Researcher Doctorate seikweng@um.edu.my E R T Tiekink Tiekink, E R T Researcher Doctorate edward.tiekink@gmail.com Files File Name Type Description  31560.pdf pdf Abstract Back To Researches Page