Document Details
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Document Type |
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Article In Journal |
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Document Title |
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Di-μ- acetato-1:2κ2 O:O′;2:3κ3 O:O,O′-bis-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) -1κ4 N,3κ4 N-bis-(perchlorato- 2κ2 O,O′)-2-sodium-1,3-dizinc perchlorate Di-μ- acetato-1:2κ2 O:O′;2:3κ3 O:O,O′-bis-(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) -1κ4 N,3κ4 N-bis-(perchlorato- 2κ2 O,O′)-2-sodium-1,3-dizinc perchlorate |
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Subject |
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Chemistry |
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Document Language |
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English |
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Abstract |
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In the title salt, [NaZn2(CH3COO) 2(ClO4)2(C16H36N 4)2]ClO4, the macrocyclic ligand binds to the Zn2+ cations through their four amino N atoms; the Zn2+ cations are also each covalently bonded to an acetate ion. For one zinc atom, the acetate group is monodentate, and the geometry is a distorted ZnN 4O trigonal bipyramid; for the other, the acetate group is anisobidentate and the geometry is a distorted ZnN4O2 octa-hedron. The two macrocycle-zinc acetate units are bridged through a diperchloratosodium unit. In the crystal, the complex cations and uncoordinated perchlorate anions are linked by N-H⋯O hydrogen bonds. |
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ISSN |
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1600-5368 |
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Journal Name |
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Acta Crystallographica Section E: Structure Reports Online |
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Volume |
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67 |
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Issue Number |
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12 |
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Publishing Year |
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1432 AH
2011 AD |
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Article Type |
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Article |
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Added Date |
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Tuesday, January 3, 2012 |
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Researchers
| GuangChuan Chuan Ou | Ou, GuangChuan Chuan | Researcher | Doctorate | |
| Seik Weng Ng | Ng, Seik Weng | Researcher | Doctorate | seikweng@um.edu.my |
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