Document Details

Document Type : Article In Journal 
Document Title :
Synthesis and spectroscopic studies of complexes containing the Schiff base 1-acetylferrocene(thio)s
Synthesis and spectroscopic studies of complexes containing the Schiff base 1-acetylferrocene(thio)s
 
Document Language : Arabic 
Abstract : [RuCl2(CO)(2)](n) reacts with the Schiff base 1-acetylferrocenethiosemicarbazone, [Fe(eta-Cp)(eta-C(5)H(4)MeC=NNHCSNH2)] to give [Fe(eta-Cp)(eta-C(5)H(4)MeC=NNHCSNH2)RuCl2(CO)(2)] and with 1-acetylferrocenesemicarbazone [Fe(eta-Cp)(eta-C(5)H(4)MeC=NNHCONH2)] to give [Fe(eta-Cp)(eta-C(5)H(4)MeC=NNHCONH2)RuCl2(CO)(2)]. Spectroscopic data indicate that the Schiff bases act as bidentate ligands and coordinate to ruthenium via the hydrazinic N and either the S or O atoms, respectively, giving stable heterobimetallic complexes, which have been characterized by i.r. and H-1-n.m.r. spectroscopies, and elemental analyses. 
Journal Name : TRANSITION METAL CHEMISTRY 
Volume : 21 
Issue Number : 1 
Publishing Year : 1996 AH  
Added Date : Saturday, June 14, 2008 

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أحمد عمر بغلف Researcher  

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